PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response
- 5 March 2012
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 48 (35) , 4220-4222
Abstract
A new polar material containing two types of stereoactive lone-pairs has been synthesized. The unique parallel alignment of the stereoactive lone-pairs on Pb2+ cations and the synergistic effect of two types of stereoactive lone-pairs on I5+ and Pb2+ cations make it exhibit a very large second-harmonic generation response of about 8 × KDP (KH2PO4).Keywords
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