Lanthanum Dependence of Elastic and Piezoelectric Properties of PLZT Ceramics with a Zr/Ti Ratio of 65/35

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Abstract
The elastic and piezoelectric properties of PLZT ceramics with a 65/35 Zr/Ti ratio undergo pronounced changes as La is added to the structure. At the rhombohedral‐tetragonal phase boundary, material constants plotted as functions of La concentration show strong discontinuities in slope; these discontinuities provide a precise means of locating the boundary. The radial‐mode coupling factor, k p , compliance coefficient, S 11 E , and piezoelectric coefficient, d 31 , attain peak values at the boundary, whereas Poisson's ratio, σ E , and the resonance‐frequency constant exhibit pronounced minima. This behavior is evidence of the increasing ferroelastic sensitivity of the material as the distortion angle of the rhombohedral phase approaches a minimum.

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