Vibrational and Vibronic Structure in the Valence Electron Spectrum of H2S

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Abstract
The high resolution HeI induced electron spectrum of H2S is presented and the energies of the observed vibrational and vibronic bands are reported. In the2B1electron band two progressions of vibrational bands have been measured. In the2A1electron band the vibronic structure associated withv2bending vibrations has been partially resolved. Assignments of the vibronic bands are suggested from a comparison with electronic emission data in terms of the vibrational and angular momentum quantum numbersv2andK.

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