ansa‐Ruthenium(II) Complexes of R2NSO2DPEN‐(CH2)n(η6‐Aryl) Conjugate Ligands for Asymmetric Transfer Hydrogenation of Aryl Ketones
- 3 August 2015
- journal article
- update
- Published by Wiley in Advanced Synthesis & Catalysis
- Vol. 357 (11) , 2540-2546
Abstract
New 3rd generation designer ansa‐ruthenium(II) complexes featuring N,C‐alkylene‐tethered N,N‐dialkylsulfamoyl‐DPEN/η6‐arene ligands, exhibited good catalytic performance in the asymmetric transfer hydrogenation (ATH) of various classes of (het)aryl ketones in formic acid/triethylamine mixture. In particular, benzo‐fused cyclic ketones furnished 98 to >99.9% ee using a low catalyst loading. magnified imageKeywords
Funding Information
- Ministry of Higher Education, Science, and Technology of the Republic of Slovenia (P1-242)
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