Orientation of surfactant molecules at a liquid-air interface measured by optical second-harmonic generation

Authors:
  • PVP. Valint
    P. Valint

Abstract
The average molecular orientation of a monolayer of sodium-dodecylnaphthalene-sulfonate on a water-air interface has been determined by use of optical second-harmonic generation. The molecular orientation is shown to vary smoothly with increasing surface density of the molecules.

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