Bidentate bis(NHC-carboxylate) palladium and nickel complexes for the hydrosilylative reduction of carbonyl compounds
Open Access
- 23 March 2026
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in RSC Advances
- Vol. 16 (18) , 16687-16693
Abstract
Pd( ii ) and Ni( ii ) biscarbene complexes bearing κ 2 -C,O-NHC carboxylate chelating ligands were synthesized and tested in aldehyde and ketone hydrosilylation. The activity showed by a Ni complex is supported by DFT analysis of ligand effects.Keywords
Funding Information
- Comunidad de Madrid (EPU-INV/2020/013)
- Ministerio de Ciencia e Innovación (PID2020-114637GB-I00)
- Universidad de Alcalá (GP2025-03)
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