Between Order and Confusion: Clearing up Structural Misconceptions in Carbon Materials Nomenclature
Open Access
- 3 February 2026
- journal article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 65 (11) , e19975
Abstract
Carbon materials are of increasing importance for various applications especially in the field of energy storage and conversion as well as electrocatalysis, and thus, they are essential for the worldwide transition toward an emission‐free economy. Hence, various carbonaceous materials with different levels of order of graphene stacks are discussed in current literature. However, precise characterization or even the correct terminology of the respective material is often neglected, leading to miscommunication and misinterpretation throughout the carbon community, especially with respect to “amorphous” carbon. Here, we aim to clarify the terms describing different graphene‐containing carbon materials, namely graphite, graphitic carbon, non‐graphitic carbon, and amorphous carbon. We recall the IUPAC definitions of these materials and correlate them with characteristic X‐ray scattering patterns as well as Raman spectra, being the most widespread and appropriate characterization techniques. Thereby, this scientific perspective strives toward raising awareness for fine structural differences and the need for a consistent characterization and description of these carbon materials.Keywords
Funding Information
- Deutsche Forschungsgemeinschaft (390874152)
This publication has 59 references indexed in Scilit:
- Revisiting Lithium‐ and Sodium‐Ion Storage in Hard Carbon AnodesAdvanced Materials, 2023
- Hard‐Carbon Anodes for Sodium‐Ion Batteries: Recent Status and Challenging PerspectivesAdvanced Energy and Sustainability Research, 2022
- Dimensionality, Function and Performance of Carbon Materials in Energy Storage DevicesAdvanced Energy Materials, 2021
- Peering into the structural evolution of glass-like carbons derived from phenolic resin by combining small-angle neutron scattering with an advanced evaluation method for wide-angle X-ray scatteringCarbon, 2019
- Analysis of thermally induced changes in the structure of coal tar pitches by an advanced evaluation method of X-ray scattering dataCarbon, 2016
- Temperature evolution of microstructure of turbostratic high melting coal-tar synthetic pitch studied using wide-angle X-ray scattering methodCarbon, 2015
- Amorphous Carbon under 80 kV Electron Irradiation: A Means to Make or Break GrapheneAdvanced Materials, 2012
- Resonance Raman spectroscopy of graphite and graphenePhysica Status Solidi (b), 2011
- Measuring the degree of stacking order in graphite by Raman spectroscopyCarbon, 2008
- A reconsideration of the relationship between the crystallite size La of carbons determined by X-ray diffraction and Raman spectroscopyCarbon, 2006