Chemoselectivity Switching in the Rhodium‐Catalyzed Reactions of 4‐Substituted‐1‐sulfonyl‐1,2,3‐triazoles with Allenols: Noticeable Differences between 4‐Acyl‐ and 4‐Aryl‐Triazoles
- 27 December 2018
- journal article
- research article
- Published by Wiley in Advanced Synthesis & Catalysis
- Vol. 361 (5) , 1160-1165
Abstract
Tunable chemoselectivity (O‐ versus C‐attack) in the rhodium‐catalyzed reactions of allenols with 4‐substituted‐1‐sulfonyl‐1,2,3‐triazoles has been achieved through the replacement of the 4‐aryl substituent by a 4‐acetyl moiety. magnified imageKeywords
Funding Information
- MINECO
- Federación Española de Enfermedades Raras (CTQ2015-65060-C2-1-P, CTQ2015-65060-C2-2-P, CTQ2016-78205-P, CTQ2016-81797-REDC)
- Federación Española de Enfermedades Raras
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