π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons

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Abstract
Three‐dimensional covalent organic frameworks (3D COFs) with a pcu topology have been obtained from distorted polycyclic aromatic hydrocarbons acting as triangular antiprismatic (D3d) nodes. Such 3D COFs are six‐fold interpenetrated as the result of interframework π‐stacking, which enable charge transport properties that are not expected for 3D COFs.

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