Anionic block copolymerization of ϵ‐caprolactam
Authors:
- 1 September 1979
- journal article
- research article
- Published by Wiley in Journal of Polymer Science: Polymer Chemistry Edition
- Vol. 17 (9) , 2903-2916
Abstract
ϵ‐Caprolactam anionic homopolymerization was studied in the presence of different model activators. On the basis of the results ester‐ and isocyanate‐terminated polymers were used as macroactivators and nylon‐6–polyvinyl or polydiene block copolymers were synthesized in high yields. The physical properties and morphology of a nylon–polybutadiene triblock copolymer were characterized.Keywords
This publication has 11 references indexed in Scilit:
- Blocked isocyanatesProgress in Organic Coatings, 1975
- Block polymers from isocyanate‐terminated intermediates. II. Preparation of butadiene–ϵ‐caprolactam and styrene–ϵ‐caprolactam block polymersJournal of Polymer Science: Polymer Chemistry Edition, 1974
- ObituaryThe Lancet, 1973
- Molecular motion in a copolymer of styrene and maleic anhydridePolymer, 1973
- Block copolymerization. VIII. Anionic polymerization of α‐pyrrolidone by polystyrene initiatorJournal of Polymer Science: Polymer Chemistry Edition, 1973
- Block copolymerization. V. Block anionic polymerization of lactamsJournal of Polymer Science Part A-1: Polymer Chemistry, 1972
- Lactam PolymerizationJournal of Macromolecular Science: Part A - Chemistry, 1972
- Anionic polymerization of caprolactam—XXXIX. Number of polymer molecules formed per molecule of acyl caprolactam in high-temperature polymerizationEuropean Polymer Journal, 1971
- The analysis of organolithium compoundsJournal of Organometallic Chemistry, 1964
- The Reaction of Amides with Isocyanates. II. N-Substituted AmidesJournal of the American Chemical Society, 1949