Light Mediated Preparation of Palladium Nanoparticles as Catalysts for Alkyne cis-Semihydrogenation
Authors:
- 9 May 2017
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 19 (10) , 2658-2661
Abstract
A bisacylphosphine oxide photoinitiator was used for the light mediated preparation of palladium nanoparticles (PdNPs) with a small diameter of 2.8 nm. All starting materials are commercially available, and PdNP synthesis is experimentally very easy to conduct. The PdNP-hybrid material was applied as catalyst for the semihydrogenation of various internal alkynes to provide the corresponding alkenes in excellent yields (up to 99%) and Z-selectivities (Z/E ratios up to 99/1).Keywords
Funding Information
- Deutsche Forschungsgemeinschaft (SFB 858)
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