Abstract
We report that a solution‐processed vanadium pentoxide (V2O5) layer can be utilized as an effective and stable hole injection layer in organic light‐emitting diodes and polymer light‐emitting diodes instead of polyethylene dioxythiophene : polystyrenesulfonate (PEDOT : PSS). The organic light‐emitting diode and polymer light‐emitting diode with the V2O5 layer have driving voltages that are 2.2 and 0.3 V lower for 1000 cd/m2, respectively, than the devices with PEDOT : PSS. In addition, the devices with the V2O5 layer show improved operational stability compared with the devices with PEDOT : PSS. Therefore, a solution‐processed V2O5 layer can be utilized as an effective and stable hole injection layer instead of PEDOT : PSS.

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