Simulation of dry reforming of methane in a conventional downfired reformer
- 10 November 2016
- journal article
- research article
- Published by Wiley in AIChE Journal
- Vol. 63 (6) , 2060-2071
Abstract
A model for industrial top‐fired dry reforming of methane (DRM) and for combined dry reforming and steam reforming of methane was developed for the first time. The model calculates and gives predictions on the temperature profiles for fuel gas, tube walls, and process gas, as well as the process gas composition profiles over the length of the tubes. Radiative heat transfer is modeled by Hottel Zone method. Material and energy balances are solved numerically using Newton‐Raphson solver. Kinetic models for two different DRM catalysts are applied in the model for comparison. Simulation results show that water–gas shift reaction is important in DRM and addition of steam in the feed of process gas is beneficial for industrial production. © 2016 American Institute of Chemical Engineers AIChE J, 63: 2060–2071, 2017Keywords
Funding Information
- Queen's University
- Natural Sciences and Engineering Research Council of Canada
This publication has 57 references indexed in Scilit:
- Continued global warming after CO2 emissions stoppageNature Climate Change, 2013
- Greenhouse-gas emission targets for limiting global warming to 2 °CNature, 2009
- Kinetic Studies of Carbon Dioxide Reforming of Methane over Ni−Co/Al−Mg−O Bimetallic CatalystIndustrial & Engineering Chemistry Research, 2008
- Biofuels from microbesApplied Microbiology and Biotechnology, 2007
- Bioethanol from Cellulosic Materials: A Renewable Motor Fuel from BiomassEnergy Sources, 2005
- Global Warming and Tropical Land-Use Change: Greenhouse Gas Emissions from Biomass Burning, Decomposition and Soils in Forest Conversion, Shifting Cultivation and Secondary VegetationClimatic Change, 2000
- Carbon Dioxide Reforming of Methane To Produce Synthesis Gas over Metal-Supported Catalysts: State of the ArtEnergy & Fuels, 1996
- Alcohol synthesis from syngasApplied Catalysis A: General, 1993
- Investigation of the synthesis of oxygenates from carbon monoxide/hydrogen mixtures on supported rhodium catalystsApplied Catalysis A: General, 1992
- Intrinsic kinetics of the Fischer-Tropsch synthesis on a cobalt catalystEnergy & Fuels, 1991