Superoleophobic Behavior Induced by Nanofeatures on Oleophilic Surfaces

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Abstract
The control of surface wetting properties to produce robust and strong hydrophobic and oleophobic effects on intrinsically oleophilic surfaces is at the heart of many technological applications. In this paper, we explore the conditions to observe such effects when the roughness of the substrate is of fractal nature and consists of nanofeatures obtained by the ion track etching technique. The wetting properties were investigated using eight different liquids with surface tensions γ varying from 18 to 72 mN m−1.While it is observed that all the tested oils readily wet the flat substrates, it is found that the contact angles are systematically exalted on the rough surfaces even for the liquids with very low surface tension. For liquids with γ ≥ 25 mN m−1 an oleophobic behavior is clearly induced by the nanostructuration. For liquids with γ < 25 mN m−1, although the contact angle is enhanced on the nanorough surfaces, it conserves its oleophilic character (θ* lower than 90°). Moreover, our experiments show that even in the case of hexane, liquid having the lowest surface tension, the homogeneous wetting (Wenzel state) is never reached. This high resistance to liquid impregnation is discussed within the framework of recent approaches explaining the wetting properties of superoleophobic surfaces.

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