Oxygen-Carrying Properties of a Simple Synthetic System
Author:
- 17 May 1963
- journal article
- other
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 140 (3568) , 809-810
Abstract
An iridium compound, chloro-carbonyl- bis (triphenylphosphine)-iridium, in solution, takes up molecular oxygen—one molecule per metal atom—which is subsequently recovered by reducing the pressure. The adduct is photosensitive but otherwise stable at ambient temperatures. It is a monomeric molecular complex and probably contains a peroxo group with both oxygens bonded to the same metal atom.Keywords
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