Copper nitrite reduction by thiols: mechanistic insights into NO release en route to copper thiolate formation
- 23 March 2026
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 55 (17) , 6854-6862
Abstract
β-Diketiminato Cu( ii )–nitrito complexes react with thiols ( t BuBzSH, BzSH, l -cysteine) to release NO and form a free ligand, disulfide, and an insoluble polymeric Cu( i )–thiolate (YP R ).Keywords
Funding Information
- National Science and Technology Council (NSTC 113-2113-M-037-006)
- Kaohsiung Medical University (KMU-TB114009-2)
- Kaohsiung Medical University (KMUH-DK(B)-114006-1)
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