Microwave Spectrum of a Silicon Monoxide Isotopomer: [TSUP]28[/TSUP]S[CLC]i[/CLC][TSUP]18[/TSUP]O

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Abstract
The rotational transitions of 28Si18O in the ground vibrational state were observed by laboratory microwave spectroscopy for astronomical use. The SiO molecules were generated in a free-space absorption cell by dc-glow discharge in a mixture of tetra-methyl silane, Si(CH3)4, and 18O2. Ten rotational transitions were precisely measured in the 40-444 GHz region. The rotational and centrifugal distortion constants were determined by a least-squares analysis of measured line frequencies: B0=20176.4394(43) and D0=0.025809(32) MHz, with the 3 σ deviations in parentheses.

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