Abstract
The structures of several uniform ··· D+A.−D+A.−D+A.−··· (D: S = 2 Mporphryin; A: S = 1/2 TCNE) chain compounds with the [TCNE].− trans-μ2 bonded to two Mn(III)'s exhibiting cooperative magnetic properties have been studied by single crystal x-ray diffraction. Herein we summarize the structures obtained for these compounds and their vCN infrared absorptions.

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