Persistent organic room temperature phosphorescence: what is the role of molecular dimers?

Authors:

Abstract
Molecular dimers have been frequently found to play an important role in room temperature phosphorescence (RTP), but its inherent working mechanism has remained unclear. Herein a series of unique characteristics, including singlet excimer emission and thermally activated delayed fluorescence, were successfully integrated into a new RTP luminogen of CS-2COOCH3 to clearly reveal the excited-state process of RTP and the special role of molecular dimers in persistent RTP emission.
Funding Information
  • Tianjin University
  • National Natural Science Foundation of China (51903188)
  • Natural Science Foundation of Tianjin Municipality (19JCQNJC04500)

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