An unprecedented twofold interpenetrating (3,4)-connected 3-D metal–organic framework

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Abstract
An unprecedented twofold interpenetrating (3,4)-connected topology of the Cu3L4-type metal–organic framework was prepared using N,N′,N″-tris(4-pyridinyl)-1,3,5-benzenetricarboxamide (L) as a trigonal three-connection node and the copper(II) ion as a square planar four-connection node, where the framework contains remarkably large 1-D solvent channels.

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