An unprecedented twofold interpenetrating (3,4)-connected 3-D metal–organic framework
Authors:
- 30 March 2007
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 17,p. 1707-1709
Abstract
An unprecedented twofold interpenetrating (3,4)-connected topology of the Cu3L4-type metal–organic framework was prepared using N,N′,N″-tris(4-pyridinyl)-1,3,5-benzenetricarboxamide (L) as a trigonal three-connection node and the copper(II) ion as a square planar four-connection node, where the framework contains remarkably large 1-D solvent channels.Keywords
This publication has 48 references indexed in Scilit:
- Nanochannel‐Promoted Polymerization of Substituted Acetylenes in Porous Coordination PolymersAngewandte Chemie International Edition, 2006
- Crystallized Frameworks with Giant Pores: Are There Limits to the Possible?Accounts of Chemical Research, 2005
- Design, Chirality, and Flexibility in Nanoporous Molecule-Based MaterialsAccounts of Chemical Research, 2005
- Metal-organic frameworksChemical Society Reviews, 2003
- Reticular synthesis and the design of new materialsNature, 2003
- Crystal Engineering of NLO Materials Based on Metal−Organic Coordination NetworksAccounts of Chemical Research, 2002
- A net-based approach to coordination polymers †J. Chem. Soc., Dalton Trans., 2000
- Frameworks for Extended Solids: Geometrical Design PrinciplesJournal of Solid State Chemistry, 2000
- Interpenetrating Nets: Ordered, Periodic EntanglementAngewandte Chemie International Edition, 1998
- Note on 3D (3,4)-connected netsActa Crystallographica Section A Foundations of Crystallography, 1986