Encapsulation of Chaotropic closo‐Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations

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Abstract
This paper deals with the formation of host‐guest systems between cyclodextrins and the closo‐decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI‐MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.
Funding Information
  • Institut Universitaire de France (‐)
  • Azm and Saade Association (‐)
  • Generalitat de Catalunya (2017SGR629)

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