Synthesis, crystal and molecular structure of the first metal complex [Pt(PPh 3 ) 2 {η 2 -AsC(C 6 H 2 Bu t 3 )}] derived from an arsaalkyne
Authors:
- Peter B. HitchcockPHPeter B. Hitchcock
- Cameron JonesCJCameron Jones
- John F. NixonJNJohn F. Nixon
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 2061-2062
Abstract
Treatment of [Pt(PPh3)2(C2H4)] with AsC(C6H2But 3) affords the title compound, the X-ray crystal structure of which shows the arsaalkyne ligand to be η2-ligated; the X-ray crystal structure of the parent arsaalkyne is also reported.Keywords
This publication has 9 references indexed in Scilit:
- Synthesis and Structure of the Arsaalkyne Tetramer (AsCtBu)4 and its Fe(CO)4 DerivativeAngewandte Chemie International Edition, 1993
- Coupled electron pair calculations for R-C E molecules (E = N, P, As or Sb)Journal of Molecular Structure: THEOCHEM, 1992
- Coordination chemistry of compounds containing phosphorus-carbon multiple bondsChemical Reviews, 1988
- Synthesis and Structure of the First Arsaalkenyl Complex with FeAs Single BondAngewandte Chemie International Edition, 1986
- 2‐(2,4,6‐Tri‐tert‐butylphenyl)‐1‐arsaethyne—the First Compound Containing an Arsenic–Carbon Triple BondAngewandte Chemie International Edition, 1986
- Photoelectron spectra of the phospha-alkynes: 3,3-dimethyl-1-phosphabutyne ButCP and phenylphosphaethyne, PhCPJ. Chem. Soc., Dalton Trans., 1983
- Organocobalt cluster complexes. 34. Preparation, properties, and chemical reactivity of phospha- and arsaacetylenedicobalt hexacarbonyl complexes, (RCM)Co2(CO)6 (M = P, As)Organometallics, 1982
- Novel transition metal phospha-alkyne complexes. X-Ray crystal and molecular structure of a side-bonded Bu t CP complex of zerovalent platinum, Pt(PPh 3 ) 2 (Bu t CP)Journal of the Chemical Society, Chemical Communications, 1981
- Molecular Spectra and Molecular Structure1979