Influence of phosphorus-based flame retardants on polypropylene insulation for high-voltage power cable applications

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Abstract
For high voltage (HV) power cable applications, various studies have been performed to improve the mechanical and electrical properties of polypropylene (PP)-based insulation materials to replace crosslinked polyethylene. However, studies on the effect of additives to yield additional PP properties are still lacking. Herein, we prepared PP blends by melt-mixing widely used commercial flame retardants for PP with isotactic PP (iPP) and investigated their electrical breakdown, flame retardancy behaviors, and UV stability. Among the five kinds of flame retardants employed, aluminum hypophosphite (AHP), aluminum diethyl phosphinate, melamine pyrophosphate, ammonium polyphosphate (APP), and APP treated with silane, AHP was very effective in minimizing the decrease of the direct current breakdown strength of iPP at both 25 °C and 110 °C in the range of 5–20 phr. Particularly, only AHP afforded V-2 grade flame retardancy to iPP, and the flame retardancy was maintained even when the content was reduced to 3 phr. Furthermore, upon exposure to ultraviolet (UV) rays for 5 d, the tensile strength of pristine iPP decreased by approximately 44%, while that of a blend with 3 phr AHP decreased by only 10%. The study results will contribute to the optimization of power cable products through the use of appropriate flame retardants in the design of high-performance PP-based HV insulation materials.

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