Sputter Synthesis of Ba2YCu3Oy As-Deposited Superconducting Thin Films from Stoichiometric Target–A Mechanism of Compositional Deviation and Its Control

Authors:
  • NTNorio Terada
    Norio Terada
  • HIHideo Ihara
    Hideo Ihara
  • MJMasatoshi Jo
    Masatoshi Jo
  • MHMasayuki Hirabayashi
    Masayuki Hirabayashi
  • YKYoichi Kimura
    Yoichi Kimura
  • KMKatsuhiro Matsutani
    Katsuhiro Matsutani
  • KHKazuo Hirata
    Kazuo Hirata
  • EOEizo Ohno
    Eizo Ohno

Abstract
A mechanism of compositional deviation of Ba-Y-Cu-O films during sputtering has been investigated, and a process for obtaining as-deposited superconducting films from a stoichiometric target has been developed. The main factor of the deviation is the radiation of high-energy electrons emitted from the oxide target with a low work function onto the growing surface. By eliminating the electron bombardment, films with the same composition were obtained reproducibly. As-grown films 4000 Å thick deposited at 580°C showed T c ( ρ=0) of 82.5 K and an excellent surface smoothness.

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