Chiral Polymers and Polymeric Particles for Enantioselective Crystallization
- 1 December 2018
- journal article
- review article
- Published by Wiley in Israel Journal of Chemistry
- Vol. 58 (12) , 1330-1337
Abstract
Chiral polymers and chiral polymeric particles have emerged as a new and exciting field of research in recent years mainly due to their possibly applications in chiral chemistry. This paper reviews the present state of the art regarding production techniques for the synthesis and applications of chiral polymeric particles. The main methods for preparing of chiral polymeric particles such as: direct polymerization, emulsion, precipitation, and suspension polymerization of chiral monomers, are reviewed. Moreover, in this article we also present the use of chiral polymers as chiral templates for the synthesis of chiral mesoporous materials. In this review we highlighted the properties and parameters involved in the preparation of these chiral polymeric materials. The present review focuses mainly on the use of chiral polymer and chiral polymeric particles for enantioselective crystallization and enantioseparation. References of the most relevant literature published by various research groups are provided. Anyway, it is clear that chiral polymeric particles are a distinctive type of chiral nanomaterials that can find many new application in other fields like, chiral drug delivery systems, enantioselective catalysis. We hope that this review article will inspired new researchers in this field and will boost the research dealing on chiral polymeric particles especially in their implementation in new areas in chiral chemistry.Keywords
This publication has 84 references indexed in Scilit:
- Optically Active Particles of Chiral PolymersMacromolecular Rapid Communications, 2013
- Recent developments on polysaccharide-based chiral stationary phases for liquid-phase separation of enantiomersJournal of Chromatography A, 2012
- Tuning the catalytic activity of l -proline functionalized hydrophobic nanogel particles in waterChemical Science, 2012
- Aldol reactions catalyzed by l-proline functionalized polymeric nanoreactors in waterChemical Communications, 2012
- l-Proline Functionalized Polymers Prepared by RAFT Polymerization and Their Assemblies as Supported OrganocatalystsMacromolecules, 2011
- Enantioselective Separation Using Chiral Mesoporous Spherical Silica Prepared by Templating of Chiral Block CopolymersACS Applied Materials & Interfaces, 2009
- A novel type of optically active helical polymers: Synthesis and characterization of poly(N‐propargylureas)Journal of Polymer Science Part A: Polymer Chemistry, 2008
- Poly(N-vinyl α-amino acid) microspheres: a model—poly(N-vinyl α-phenyl alanine) microspheres: synthesis and characterizationColloids and Surfaces A: Physicochemical and Engineering Aspects, 2002
- Asymmetric polymerization of methacrylatesProgress in Polymer Science, 1990
- Resolution of conglomerates with the assistance of tailor-made impurities. Generality and mechanistic aspects of the "rule of reversal". A new method for assignment of absolute configurationJournal of the American Chemical Society, 1982