catena-Poly[[bis(1H-benzimidazole-κN3)(salicylato-κO)copper(II)]-μ-salicylato-O,O′:O′′]
Authors:
- 11 December 2004
- journal article
- research article
- Published by International Union of Crystallography (IUCr) in Acta Crystallographica Section C Crystal Structure Communications
- Vol. 61 (1) , m19-m21
Abstract
The title compound, [Cu(C7H5O3)2(C7H6N2)2]n, is a one-dimensional polymeric complex bridged by salicylate anions. The Cu(II) atom is surrounded by three salicylate and two benzimidazole ligands, with a tetragonally elongated octahedral coordination geometry. The Cu-O bond distances in the axial directions are 2.6092 (16) and 2.6834 (17) A. pi-pi stacking interactions exist between the benzimidazole rings of neighboring polymeric complex chains.Keywords
This publication has 3 references indexed in Scilit:
- Bis(3-methylbenzoato-κ2O,O′)(phenanthroline-κ2N,N′)copper(II)Acta Crystallographica Section E Crystallographic Communications, 2004
- Synthesis and Crystal Structure of a Polymeric Benzimidazole Complex of Mn(II) Bridged by SuccinateJournal of Coordination Chemistry, 2003
- The Cambridge Structural Database: a quarter of a million crystal structures and risingActa crystallographica Section B, Structural science, crystal engineering and materials, 2002