Saturation Magnetization of Nickel Films of Thickness Less Than 100 A

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Abstract
Nickel films varying in thickness from 200 to 3 A were prepared by evaporation on glass substrates in a vacuum sufficiently high to prevent gas adsorption on the film during preparation and measurement. Their magnetization was measured as a function of field up to 10 000 oe using a vacuum torsion magnetometer. The saturation magnetization of these films was determined as a function of their thickness at 300°K and 77°K. No decrease in saturation magnetization from that of bulk nickel has been observed for films of thickness down to 20 A, at room temperature. The Curie temperature of a 27 A film was found to coincide with that of bulk nickel. The magnetic behavior of films in the thickness range below 20 A suggests superparamagnetism rather than a decrease in the saturation magnetization. Measurements of the magnetostrictive anisotropy constant indicate that the films as originally prepared are in a state of high tensile strain, which can be relieved by annealing. The thin film nature of some specimens was ascertained by examination in the electron microscope.

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