Improvement of the corrosion resistance and structural and mechanical properties of a titanium base alloy by thermo‐mechanical processing
- 16 May 2012
- journal article
- research article
- Published by Wiley in Materials and Corrosion
- Vol. 64 (6) , 500-508
Abstract
In this work, a new ternary Ti–25Ta–5Zr alloy (with nontoxic alloying elements) was obtained and used to develop a thermo‐mechanical procedure in order to optimize the balance strength – elastic modulus. Data about structural (by SEM) and mechanical properties are investigated. Also, its electrochemical behaviour in Ringer–Brown and Ringer solutions of different pH values (simulating severe functional conditions of an implant) was studied by cyclic potentiodynamic and linear polarization and electrochemical impedance spectroscopy (EIS). From cyclic potentiodynamic polarization curves it resulted the nobler behaviour of the thermo‐mechanical treated alloy than as‐cast alloy due to the favourable influence of the applied processing. Impedance spectra were fitted with one time constant equivalent circuit characterizing a very stable, resistant oxide passive film. The values of the open circuit potentials for the treated alloy are nobler than of the as‐cast alloy and tended to more positive values in time, proving that the passive film on its surface is more compact and thickened in time.Keywords
Funding Information
- Romanian Academy
This publication has 46 references indexed in Scilit:
- Synthesis and characterisation of a new superelastic Ti–25Ta–25Nb biomedical alloyJournal of the Mechanical Behavior of Biomedical Materials, 2010
- Effect of Sn addition on the corrosion behavior of Ti‐Ta alloyMaterials and Corrosion, 2010
- Corrosion behavior of Ti‐xNb‐13Zr alloys in Ringer's solutionMaterials and Corrosion, 2008
- Investigation of the electrochemical behaviour and surface chemistry of a Ti‐13Nb‐13Zr alloy exposed in MEM cell culture media with and without the addition of H 2 O 2Surface and Interface Analysis, 2008
- In vitro corrosion behaviour of Ti‐5Al‐2Nb‐1Ta alloy in Hanks solutionMaterials and Corrosion, 2007
- Influence of fluoride concentration and pH on corrosion behavior of Ti‐6Al‐4V and Ti‐23Ta alloys in artificial salivaMaterials and Corrosion, 2007
- Corrosion characterization of titanium alloys by electrochemical techniquesElectrochimica Acta, 2006
- Biocompatibility of β-stabilizing elements of titanium alloysBiomaterials, 2004
- Corrosion susceptibility of implant materials Ti–5Al–4V and Ti–6Al–4Fe in artificial extra-cellular fluidsElectrochimica Acta, 2004
- Corrosion and Passivity of Ti-13% Nb-13% Zr in Comparison to Other Biomedical Implant AlloysCorrosion, 1997