Comparison Between Crystalline and Amorphous Silicon as Anodes for Lithium Ion Batteries: Electrochemical Performance from Practical Cells and Lithiation Behavior from Molecular Dynamics Simulations

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Abstract
As a prominent next-generation anode material for high-capacity applications, silicon stands out due to its potential. Crystalline silicon, which offers a higher initial capacity compared to its amorphous counterpart, presents challenges in practical applications due to its poor cycling performance. In this study, we prepared composites of crystalline and amorphous silicon with graphite, assembled pouch-type full cells, and evaluated their suitability for practical use. The material incorporating amorphous silicon demonstrated superior performance at both high and low rates, as well as various temperatures. Additionally, the changes in cell thickness during charge and discharge, i.e., the volume changes in the anode material, are significantly related to cycling performance. We examined the microscopic interactions between silicon and lithium atoms using molecular dynamics simulations. Our observations indicate that lithium migration within amorphous silicon, which has lower activation energy, is much easier than in crystalline silicon. In crystalline silicon, lithium penetration is greatly influenced by the orientation of the crystal planes, resulting in anisotropic volume expansion during lithiation.
Funding Information
  • the Gwangju-Jeonnam Local Energy Cluster Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) (20214000000560, GCU-202301090001, 2021R1A2C1011080)
  • Korea Institute of Energy Technology Evaluation and Planning (20214000000560, GCU-202301090001, 2021R1A2C1011080)
  • Gachon University (20214000000560, GCU-202301090001, 2021R1A2C1011080)
  • National Research Foundation of Korea (20214000000560, GCU-202301090001, 2021R1A2C1011080)

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