An Air and Thermally Stable One- Component Catalyst for the Amination of Aryl Chlorides
Authors:
- 13 June 2003
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 5 (14) , 2413-2415
Abstract
In this paper we report a new, highly efficient palladacyclic precatalyst that is air, moisture, and thermally stable and obviates the need to employ a glovebox. We have developed a convenient one-component precatalyst for the amination of aryl chlorides that overcomes many of the limitations of those previously described.Keywords
This publication has 7 references indexed in Scilit:
- Unparalleled Rates for the Activation of Aryl Chlorides and Bromides: Coupling with Amines and Boronic Acids in Minutes at Room TemperatureAngewandte Chemie International Edition, 2002
- Mechanistic Insights into the Pd(BINAP)-Catalyzed Amination of Aryl Bromides: Kinetic Studies under Synthetically Relevant ConditionsJournal of the American Chemical Society, 2002
- Sulfur-Functionalized Olefins for Titanacycle Formation: Tandem Asymmetric Cyclization and the Pummerer Reaction Based on Sulfoxides Promoted by Titanium(II)-to-Titanium(IV) RelayAngewandte Chemie International Edition, 2002
- Aqueous Hydroxide as a Base for Palladium-Catalyzed Amination of Aryl Chlorides and BromidesThe Journal of Organic Chemistry, 2002
- Reactivity studies of [Pd2(μ-X)2(PBut3)2] (X = Br, I) with CNR (R = 2,6-dimethylphenyl), H2 and alkynesJournal of Organometallic Chemistry, 2000
- β-Hydrogen-Containing Sodium Alkoxides as Suitable Bases in Palladium-Catalyzed Aminations of Aryl HalidesThe Journal of Organic Chemistry, 2000
- Palladium Alkoxides: Potential Intermediacy in Catalytic Amination, Reductive Elimination of Ethers, and Catalytic Etheration. Comments on Alcohol Elimination from Ir(III)Journal of the American Chemical Society, 1996