Organic carboxylate salt-enabled alternative synthetic routes for bio-functional cyclic carbonates and aliphatic polycarbonates
Open Access
- 8 August 2022
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Polymer Chemistry
- Vol. 13 (36) , 5193-5199
Abstract
A cyclic carbonate with an ammonium carboxylate residue was found to serve as a nucleophile for esterification with alkyl bromides via the S N 2 mechanism.Keywords
Funding Information
- Izumi Science and Technology Foundation (H24-J-129)
- Japan Science and Technology Agency (JPMJMI21EH)
- Center of Innovation Program (JPMJCE1312)
- Japan Society for the Promotion of Science (JP18K12074)
- Japan Society for the Promotion of Science (JP19H05715)
- Japan Society for the Promotion of Science (JP19H05716)
- Japan Society for the Promotion of Science (JP19H05720)
- Japan Society for the Promotion of Science (JP25870078)
- Iketani Science and Technology Foundation (0301087-A)
This publication has 31 references indexed in Scilit:
- Dual Versatility of Triazolium-Based Cyclic Carbonate Inimer: From Homopolymerization to On-Demand Thermally Activated Initiating SiteMacromolecules, 2011
- Thermoresponsive nanostructured polycarbonate block copolymers as biodegradable therapeutic delivery carriersBiomaterials, 2011
- A Simple and Efficient Synthesis of Functionalized Cyclic Carbonate Monomers Using a Versatile Pentafluorophenyl Ester IntermediateJournal of the American Chemical Society, 2010
- Revolutionary phosgene‐free synthesis of α‐amino acid N‐carboxyanhydrides using diphenyl carbonate based on activation of α‐amino acids by converting into imidazolium saltsJournal of Polymer Science Part A: Polymer Chemistry, 2010
- Water Structure and Blood Compatibility of Poly(tetrahydrofurfuryl acrylate)Journal of Biomaterials Science, Polymer Edition, 2009
- Organocatalytic Approach to Amphiphilic Comb-Block Copolymers Capable of Stereocomplexation and Self-AssemblyBiomacromolecules, 2008
- Guanidine and Amidine Organocatalysts for Ring-Opening Polymerization of Cyclic EstersMacromolecules, 2006
- Synthesis of novel bis- and tris-(cyclic carbonate)s and their use in preparation of polymer networksPolymer, 2002
- Synthesis, properties, and biodegradation of poly(1,3-trimethylene carbonate)Macromolecules, 1991
- Catalytic transfer hydrogenationChemical Reviews, 1974