Layer-by-layer synthesis of γ-Fe2O3@SnO2@C porous core–shell nanorods with high reversible capacity in lithium-ion batteries
Authors:
- 20 March 2013
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Nanoscale
- Vol. 5 (11) , 4744-4750
Abstract
We demonstrated the layer-by-layer synthesis of γ-Fe2O3@SnO2@C porous core–shell nanorods. FeOOH nanorods were first synthesized via a hydrothermal process, and acted as a template for subsequent layer-by-layer deposition. It was indicated that the electrostatic attraction between the charged species may play the key role in the formation of the core–shell nanostructures. When used as an anode material in lithium-ion batteries, γ-Fe2O3@SnO2@C porous core–shell nanorods showed high initial Coulombic efficiency, high reversible capacity, and good cycling and rate performances. The correlation between the structure, composition and electrochemical performance was also discussed.Keywords
This publication has 36 references indexed in Scilit:
- Large scale synthesis of nickel oxide/multiwalled carbon nanotube composites by direct thermal decomposition and their lithium storage propertiesJournal of Power Sources, 2011
- Large-Scale Synthesis of SnO2 Nanotube Arrays as High-Performance Anode Materials of Li-Ion BatteriesThe Journal of Physical Chemistry C, 2011
- Epitaxial Growth of Branched α‐Fe2O3/SnO2 Nano‐Heterostructures with Improved Lithium‐Ion Battery PerformanceAdvanced Functional Materials, 2011
- Assembling CoSn3 nanoparticles on multiwalled carbon nanotubes with enhanced lithium storage propertiesNanoscale, 2011
- Carbon-coated SnO2nanotubes: template-engaged synthesis and their application in lithium-ion batteriesNanoscale, 2010
- Building one-dimensional oxide nanostructure arrays on conductive metal substrates for lithium-ion battery anodesNanoscale, 2010
- Superior Lithium Electroactive Mesoporous Si@Carbon Core−Shell Nanowires for Lithium Battery Anode MaterialNano Letters, 2008
- High Capacity Li Ion Battery Anodes Using Ge NanowiresNano Letters, 2007
- Porous Indium Oxide Nanotubes: Layer‐by‐Layer Assembly on Carbon‐Nanotube Templates and Application for Room‐Temperature NH3 Gas SensorsAdvanced Materials, 2007
- α‐Fe2O3 Nanotubes in Gas Sensor and Lithium‐Ion Battery ApplicationsAdvanced Materials, 2005