The acid decomposition of 1-aryl-3,3-dialkyltriazenes. Mechanistic changes as a function of aromatic substitution, nucleophile strength, and solvent

Authors:
  • JBJorge R. Barrio
    Jorge R. Barrio
  • NSNagichettiar Satyamurthy
    Nagichettiar Satyamurthy
  • HKHao Ku
    Hao Ku
  • MPMicheal E. Phelps
    Micheal E. Phelps
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Abstract
Solvent, nucleophile strength, and substituents on the phenyl ring modified the yeild of aromatic halogenation using 1-aryl-3,3-dialkyltriazenes (2a–f) and halid ion in anhydrous acidic media.