The pressure and temperature dependence of methane decomposition

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Abstract
Single‐channel hindered Gorin model RRKM calculations were performed on reaction (1). equation image Good agreement between theory and experiment was obtained for the temperature and pressure dependence of reaction (1). Isotopic data for the reverse association reaction, (−1), reported previously, are consistent with the model. Rate constants were cast in the form of an analytical expression and appropriate parameters were tabulated.
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