Carbon tetrachloride-free allylic halogenation-mediated glycosylations of allyl glycosides
- 6 October 2021
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Organic & Biomolecular Chemistry
- Vol. 19 (42) , 9318-9325
Abstract
A one-pot CCl4-free allylic halide activation of allyl glycosides, followed by glycosylation with acceptors, is conducted in a latent-active manner. PhCF3 as the solvent and TMSOTf/Tf2O as the promoter system are optimal for the reaction.Keywords
Funding Information
- Anusandhan National Research Foundation
- Council of Scientific and Industrial Research, India
- University Grants Commission
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