Molecular Double‐Bond Covalent Radii for Elements Li–E112
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- 18 November 2009
- journal article
- research article
- Published by Wiley in Chemistry – A European Journal
- Vol. 15 (46) , 12770-12779
Abstract
The previous systems of triple‐bond and single‐bond self‐consistent, additive covalent radii, R(AB)=r(A)+ r(B), are completed with a fit for σ2π2 double‐bonds.The primary bond lengths, R, are taken from experimental or theoretical data corresponding to chosen group valencies. All r(E) values are obtained from the same, self‐consistent fit. Many of the calculated primary data came from ECH2 and HECH2 models. Homonuclear LEEL, formaldehyde‐type Group 14–Group 16 and open‐shell, X 3 Σ Group‐16 dimer data are included. The standard deviation for the 316 included data points is 3 pm.Keywords
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