Platinum(II) catalysed selective remote oxidation of unactivated C–H bonds in aliphatic carboxylic acids
Authors:
- Lien-Chung KaoLKLien-Chung Kao
- Ayusman SenASAyusman Sen
- 1 January 1991
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1242-1243
Abstract
Platinum(II) ion, in the presence of platinum(IV), is found to catalyse the hydroxylation of unactivated C–H bonds of aliphatic carboxylic acids in water with the following order of reactivity: α-C–H << β-C–H < γ-C–H δ-C–H ≈ε-C–H.Keywords
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