Scandium‐Doped Anatase (TiO 2 ) Nanoparticles Directly Formed by Hydrothermal Crystallization

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Abstract
Anatase‐type TiO 2 solid solutions doped with 0–10 mol% scandium were formed by hydrothermal crystallization under weak basic conditions above 180°C for 5 h from amorphous co‐precipitates that were obtained from the aqueous precursor solutions of TiOSO 4 and Sc(NO 3 ) 3 using aqueous ammonia. The anatase particles were spindle‐like and consisted of nanosized‐crystallites (23–25 nm). The lattice parameter c 0 of anatase and the length and width of the spindle‐like anatase gradually increased when the scandium content was increased. The diffuse reflectance spectra of the as‐prepared TiO 2 doped with scandium showed that the onset of absorption slightly shifted to longer wavelengths with increasing scandium content. The band gap of anatase was slightly increased by making solid solutions with scandium oxide.

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