Crystal size-dependent framework flexibility of a prototypical metal organic framework is related to metal content: zeolitic imidazolate framework-7

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Abstract
Reducing crystal size in ZIF-7 MOFs leads to significantly increased framework flexibility with smaller crystals exhibiting more point defects and lower metal content. Such size-dependent behaviour may enable rational design of various materials.
Funding Information
  • National Science Foundation (DMR- 2221086)
  • University of Iowa

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