Fingerprints of order and disorder on the high-frequency dynamics of liquids

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Abstract
It is largely accepted that liquids are characterized by a short-range order usually corresponding to that of the solid phase at the same density. It is less clear to what extent dynamic properties of liquids and crystals can be compared. In particular, high-frequency collective excitations reminiscent of phonons in solids exist as well in liquids. They are however traditionally discussed in terms of relaxation processes characteristic of the liquid phase. We report here on a quantitative comparison of the collective excitations in liquid and polycrystalline sodium. We show that liquid sodium exhibits acoustic excitations of both longitudinal and transverse polarization at frequencies strictly related to those of the corresponding crystal. The only relevant difference between the liquid and the polycrystal appears in the broadening of the excitations: An additional disorder-induced contribution comes into play in the case of the liquid, which we show to be related to the distribution of local structures around the average one. These results establish a direct connection between structural and dynamic properties of liquids, with short-range order and overall structural disorder leaving very specific fingerprints.

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