3D solvent-free energetic metal–organic framework (EMOF) achieved by removing inclusion molecules from a new coordination polymer

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Abstract
The reaction of CuCl and NaN3 with 4,4′-azo-1,2,4-triazol-5-one (H2ZTO) under solvothermal conditions produced a new 3D heteronuclear Cu(i)-Na(i) energetic metal–organic framework (EMOF), [Cu3Na(ZTO)2]n·nCH3CN (1).
Funding Information
  • National Natural Science Foundation of China (21673180, 21673181, 21703002, 21773185)
  • China Postdoctoral Science Foundation (2017M610646)
  • Doctoral Scientific Research Starting Foundation of Baoji University of Arts and Science (ZK2017024)
  • Northwest University (334100048)
  • Welch Foundation (BC-0022)

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