Phosphoryl-Related Directing Groups in Rhodium(III) Catalysis: A General Strategy to Diverse P-Containing Frameworks
Authors:
- 23 August 2013
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 15 (17) , 4504-4507
Abstract
Herein, a rhodium(III)-catalyzed oxidative C–H activation of simple arylphosphonates and phosphonamides with subsequent coupling with alkenes (olefination), internal alkynes (hydroarylation and oxidative cyclization), or simple arenes to give access to diverse P-containing functional frameworks is reported.Keywords
This publication has 48 references indexed in Scilit:
- Palladium-Catalyzed C–H Arylation Using Phosphoramidate as a Directing Group at Room TemperatureOrganic Letters, 2013
- Rhodium(III) and Hexabromobenzene—A Catalyst System for the Cross‐Dehydrogenative Coupling of Simple Arenes and Heterocycles with Arenes Bearing Directing GroupsAngewandte Chemie International Edition, 2012
- Access to Sultams by Rhodium(III)‐Catalyzed Directed C-H ActivationAngewandte Chemie International Edition, 2012
- C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activationChemical Society Reviews, 2012
- Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization ReactionsAccounts of Chemical Research, 2011
- Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium CatalysisChemistry – A European Journal, 2010
- Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C−H/N−H ActivationJournal of the American Chemical Society, 2010
- Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond ActivationChemical Reviews, 2009
- Biaryl Phosphane Ligands in Palladium‐Catalyzed AminationAngewandte Chemie International Edition, 2008
- Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond ActivationAccounts of Chemical Research, 2008