Nitrosation of α,β-Unsaturated Carboxamide with Nitric Oxide and Triethylsilane Catalyzed by Cobalt(II) Complex
Authors:
- 1 August 1990
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 19 (8) , 1395-1398
Abstract
In the presence of a catalytic amount of N,N′-bis(2-ethoxycarbonyl-3-oxobutylidene)ethylenediaminatocobalt(II), various α,β-unsaturated carboxamides are converted to the corresponding 2-nitrosocarboxamides regioselectively in good yields on treatment with nitric oxide and triethylsilane at room temperature.Keywords
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