Chloride ion concentration: diffusion coefficient due to Brownian motion of micro CT images
Open Access
- 1 August 2025
- journal article
- Published by Brazilian Journals in Contribuciones A Las Ciencias Sociales
- Vol. 18 (8) , e20002
Abstract
In civil construction, the materials used must maintain a sustainable approach, contributing to the lifespan of structures. The durability of cementitious materials considers chloride ion diffusion as an important factor, since corrosion caused by chloride ions compromises the lifespan of structures. In this research, the prediction of chloride ion attack depth was performed using Brownian motion modeling. The use of only the Stokes-Einstein equation was considered to obtain the diffusion coefficient. Parameters such as the diffusion coefficient and surface chloride ion concentration were predicted. The spray zone was considered in determining these parameters. In the simulation to determine depth, surface concentration, chloride ion concentration, and diffusion coefficient, the time period considered was 10 years. As predicted in several studies, chloride ion diffusion decreases with depth, as does chloride ion concentration. The importance of this research for 10-year predictions relates the behavior of chloride ion attack over time to the prediction of structural service life.Keywords
This publication has 28 references indexed in Scilit:
- Brownian motion at short time scalesAnnalen der Physik, 2013
- Ion-cement hydrate interactions govern multi-ionic transport model for cementitious materialsCement and Concrete Research, 2010
- Numerical modeling for predicting service life of reinforced concrete structures exposed to chloride environmentsCement and Concrete Composites, 2010
- Factors influencing chloride transport in concrete structures exposed to marine environmentsCement and Concrete Composites, 2008
- Tortuosity based on Anisotropic Diffusion Process in Structured Plate-like Obstacles by Monte Carlo SimulationTransport in Porous Media, 2007
- Calculation of chloride diffusion coefficients in concrete from ionic migration measurementsCement and Concrete Research, 1993
- Diffusion coefficients of sulfate and methane in marine sediments: Influence of porosityGeochimica et Cosmochimica Acta, 1993
- Mathematical description of heterogeneous materialsChemical Engineering Science, 1990
- Diffusion of chloride ions in hardened cement pastesCement and Concrete Research, 1981
- Diffusion in a pore of varying cross sectionAIChE Journal, 1958