Half-sandwich Ni(ii) complexes bearing enantiopure bidentate NHC-carboxylate ligands: efficient catalysts for the hydrosilylative reduction of acetophenones
Open Access
- 15 December 2023
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 53 (4) , 1460-1468
Abstract
Chiral [Ni(Cp)(κ2-C,O-NHC)] and [Ni(κ2-C,O-NHC)2] containing carbene-carboxylate chelate ligands derived from the (S)-isomeric form of amino acids.Keywords
Funding Information
- Ministerio de Ciencia e Innovación (PID2020-114637GB-I00)
- Comunidad de Madrid (EPU-INV/2020/013)
This publication has 76 references indexed in Scilit:
- Intramolecular Nitrile C–H Bond Activation in Nickel NHC Complexes: A Route to New NickelacyclesOrganometallics, 2011
- Controlled synthesis of nickel(ii) dihalides bearing two different or identical N-heterocyclic carbene ligands and the influence of carbene ligands on their structures and catalysisDalton Transactions, 2011
- First-row transition metal catalyzed reduction of carbonyl functionalities: a mechanistic perspectiveDalton Transactions, 2010
- N-Heterocyclic Carbenes in Late Transition Metal CatalysisChemical Reviews, 2009
- Catalytic Hydrosilylation of the Carbonyl Functionality via a Transient Nickel Hydride ComplexOrganometallics, 2009
- Hydrosilylation of Aldehydes and Ketones Catalyzed by Nickel PCP-Pincer Hydride ComplexesOrganometallics, 2008
- Thermodynamics of N-Heterocyclic Carbene Dimerization: The Balance of Sterics and ElectronicsOrganometallics, 2008
- Simple Synthesis of CpNi(NHC)Cl Complexes (Cp = Cyclopentadienyl; NHC = N-Heterocyclic Carbene)Organometallics, 2005
- Indenylnickel(II) N-Heterocyclic Carbene Complexes: Synthesis via Indene Elimination and Catalytic Activity for Ethylene DimerizationOrganometallics, 2004
- Hydrosilylation of alkenes and ketones catalyzed by nickel(II) indenyl complexesCanadian Journal of Chemistry, 2003