Sorption-enhanced mixed-gas transport in amine functionalized polymers of intrinsic microporosity (PIMs)
Open Access
- 4 October 2021
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry A
- Vol. 9 (41) , 23631-23642
Abstract
Pure-gas sorption and mixed-gas transport properties of six functionalized PIM-1 variants were systematically investigated to study the role of CO 2 affinity and polymer chemistry on competitive sorption.Keywords
Funding Information
- Office of Naval Research (N00014-21-1-2666)
- Office of Naval Research (N00014-20-1-2418)
- U.S. Department of Energy (DE-SC0019087)
- ExxonMobil Research and Engineering Company
- National Science Foundation (DGE-1745302)
- National Science Foundation (DGE-1122374)
This publication has 95 references indexed in Scilit:
- High pressure pure- and mixed-gas separation of CO2/CH4 by thermally-rearranged and carbon molecular sieve membranes derived from a polyimide of intrinsic microporosityJournal of Membrane Science, 2013
- Polymers of intrinsic microporosity (PIMs) substituted with methyl tetrazolePolymer, 2012
- Sub-Tg Cross-Linking of a Polyimide Membrane for Enhanced CO2 Plasticization Resistance for Natural Gas SeparationMacromolecules, 2011
- Predictive Model for the Solubility of Fluid Mixtures in Glassy PolymersMacromolecules, 2011
- Effect of molecular weight and temperature on physical aging of thin glassy poly(2,6‐dimethyl‐1,4‐phenylene oxide) filmsJournal of Polymer Science Part B: Polymer Physics, 2007
- Sorption of CO2, C2H4, N2O and their binary mixtures in poly(methyl methacrylate)Journal of Polymer Science Part B: Polymer Physics, 1986
- Dual-mode transport of penetrants in glassy polymersMacromolecules, 1985
- Pure and mixed gas sorption of carbon dioxide and ethylene in poly(methyl methacrylate)Journal of Membrane Science, 1984
- Energetics of gas sorption in glassy polymersPolymer, 1979
- Effect of immobilizing adsorption on the diffusion time lagJournal of Polymer Science Part A-2: Polymer Physics, 1969