Enhancement of the Visible-Light Photocatalytic Activity of In2O3–TiO2 Nanofiber Heteroarchitectures
- 28 December 2011
- journal article
- research article
- Published by American Chemical Society (ACS) in ACS Applied Materials & Interfaces
- Vol. 4 (1) , 424-430
Abstract
One-dimensional In2O3–TiO2 heteroarchitectures with high visible-light photocatalytic activity have been successfully obtained by a simple combination of electrospinning technique and solvothermal process. The as-obtained products were characterized by field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray (EDX) spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and UV–vis spectra. The results revealed that the secondary In2O3 nanostructures were successfully grown on the primary TiO2 nanofibers substrates. Compared with the pure TiO2 nanofibers, the obtained In2O3–TiO2 heteroarchitectures showed enhancement of the visible-light photocatalytic activity to degrade rhodamine B (RB) because of the formation of heteroarchitectures, which might improve the separation of photogenerated electrons and holes derived from the coupling effect of TiO2 and In2O3 heteroarchitectures. Moreover, the In2O3–TiO2 heteroarchitectures could be easily recycled without the decrease in the photocatalytic activity because of their one-dimensional nanostructural property.Keywords
This publication has 50 references indexed in Scilit:
- One‐Step Solvothermal Synthesis of a Carbon@TiO2 Dyade Structure Effectively Promoting Visible‐Light PhotocatalysisAdvanced Materials, 2010
- Carbon-Deposited TiO2: Synthesis, Characterization, and Visible Photocatalytic PerformanceThe Journal of Physical Chemistry C, 2009
- Slurry photodegradation of 2,4-dichlorophenoxyacetic acid: A comparative study of impregnated and sol–gel In2O3–TiO2 mixed oxide catalystsJournal of Photochemistry and Photobiology A: Chemistry, 2008
- Synthesis of TiO2 particles by reverse microemulsion method using nonionic surfactants with different hydrophilic and hydrophobic group and their photocatalytic activityCatalysis Today, 2005
- X-ray photoelectron spectroscopy studies of indium tin oxide nanocrystalline powderMaterials Characterization, 2005
- TiO2-In2O3 photocatalysts: preparation, characterisations and activity for 2-chlorophenol degradation in waterJournal of Photochemistry and Photobiology A: Chemistry, 2004
- Photochromism of WO3 Colloids Combined with TiO2 NanoparticlesThe Journal of Physical Chemistry B, 2002
- An XPS study of La2O3 and In2O3 influence on the physicochemical properties of MoO3/TiO2 catalystsApplied Catalysis A: General, 2001
- Visible-Light Photocatalysis in Nitrogen-Doped Titanium OxidesScience, 2001
- Semiempirical Correlation between Optical Band Gap Values of Oxides and the Difference of Electronegativity of the Elements. Its Importance for a Quantitative Use of Photocurrent Spectroscopy in Corrosion StudiesThe Journal of Physical Chemistry B, 1997