Synthesis of sequence controlled acrylate oligomers via consecutive RAFT monomer additions
Open Access
- 17 September 2013
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 49 (88) , 10358-10360
Abstract
An effective procedure to synthesize sequence controlled oligoacrylates with up to four monomer insertions via the RAFT technique is presented. Two different sets of oligomers with a preferred monomer order were synthesized. Recycling SEC allowed for facile and automated purification of the monodisperse sequence-controlled materials.Keywords
This publication has 25 references indexed in Scilit:
- Single-chain technology using discrete synthetic macromoleculesNature Chemistry, 2011
- New Features of the Mechanism of RAFT Polymerization2009
- Selective Radical Addition with a Designed Heterobifunctional Halide: A Primary Study toward Sequence-Controlled Polymerization upon Template EffectJournal of the American Chemical Society, 2009
- The role of mid‐chain radicals in acrylate free radical polymerization: Branching and scissionJournal of Polymer Science Part A: Polymer Chemistry, 2008
- Initialization behavior at various target molecular weight RAFT‐mediated methyl acrylate polymerizationsJournal of Polymer Science Part A: Polymer Chemistry, 2008
- Clicking polymers: a straightforward approach to novel macromolecular architecturesChemical Society Reviews, 2007
- Controlled/living radical polymerization: Features, developments, and perspectivesProgress in Polymer Science, 2007
- Atom Transfer Radical PolymerizationChemical Reviews, 2001
- Sequence-regulated oligomers and polymers by living cationic polymerization. 2. Principle of sequence regulation and synthesis of sequence-regulated oligomers of functional vinyl ethers and styrene derivativesMacromolecules, 1990
- Solid Phase Peptide Synthesis. I. The Synthesis of a TetrapeptideJournal of the American Chemical Society, 1963