Single-crystal growth of coordination networks via the gas phase and dependence of iodine encapsulation on the crystal size
Authors:
Open Access
- 8 September 2014
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 50 (89) , 13793-13796
Abstract
Self-assembly of the tripyridyl ligand 2,4,6-tris(4-pyridyl)triazine(TPT) and ZnI2via the gas phase produced three kinds of networks: [(ZnI2)(TPT)]n; [(ZnI2)3(TPT)2]n; and [(ZnI2)(μ-I)(ZnI)(TPT)]n. [(ZnI2)3(TPT)2]n is the first example of the single crystal formation of a porous network via the gas phase and showed the dependence of iodine encapsulation on the crystal size.Keywords
This publication has 57 references indexed in Scilit:
- Hybrid porous solids: past, present, futureChemical Society Reviews, 2007
- Molecular Tectonics: From Simple Tectons to Complex Molecular NetworksAccounts of Chemical Research, 2005
- From Molecules to Crystal Engineering: Supramolecular Isomerism and Polymorphism in Network SolidsChemical Reviews, 2001
- Interpenetrating Nets: Ordered, Periodic EntanglementAngewandte Chemie International Edition, 1998
- Three‐Dimensional Framework with Channeling Cavities for Small Molecules: {[M2(4, 4′‐bpy)3(NO3)4]·xH2O}n (M Co, Ni, Zn)Angewandte Chemie International Edition, 1997
- Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular ChannelsJournal of the American Chemical Society, 1995
- Preparation, Clathration Ability, and Catalysis of a Two-Dimensional Square Network Material Composed of Cadmium(II) and 4,4'-BipyridineJournal of the American Chemical Society, 1994
- Interwoven two- and three-dimensional coordination polymers through self-assembly of Cu I cations with linear bidentate ligandsJournal of the Chemical Society, Chemical Communications, 1994
- Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4][CuIZnII(CN)4] and CuI[4,4',4'',4'''-tetracyanotetraphenylmethane]BF4.xC6H5NO2Journal of the American Chemical Society, 1990
- Infinite polymeric frameworks consisting of three dimensionally linked rod-like segmentsJournal of the American Chemical Society, 1989