Planarization of tetracarboxamides: tuning the self-assembly of polycyclic aromatic hydrocarbons
- 29 April 2019
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 55 (43) , 6070-6073
Abstract
The geometry-dependent self-assembling features of two PAHs, 1 and 2, are reported. The more planar 1 forms H-type supramolecular polymers, in a highly cooperative fashion, by a combination of H-bonding and π-stacking, with rod-like morphology. However, the highly distorted 2 interacts only by means of H-bonding with no contact between the aromatic units, yielding lamellar supramolecular structures.Keywords
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